Lab 12: Alka Seltzer and the Ideal Gas Law
In this lab, my lab partner Meghana and I practiced using the ideal gas law to find the mass of CO2 in a balloon after the reaction between sodium bicarbonate and citric acid occurred within the balloon and a test tube below it. Since dissolving the two substances (both in an alka seltzer tablet) in water lets them react, we placed a balloon filled with the crushed tablets over a test tube of water. When we flipped the balloon over and let the contents into the water, they reacted and CO2 was released into the balloon. The circumference of the balloon and the amount of water that filled the balloon creating the same circumference were used to find the mass of CO2 in the balloon.
1. Discuss an area in this lab where experimental error may have occurred.
Experimental error may have occurred when transferring the crushed tablet powder from the weigh boat to the balloon; some of the powder could have missed the balloon, decreasing the amount of sodium bicarbonate and citric acid that reacted. Another area could also have been while pouring the water from the balloon into the graduated cylinder, some of the water missed, resulting in less water being measured as the volume of the balloon. The measurement of the circumference could have also been wrong, since the balloon wasn't spherical and was very misshapen, and it was difficult to find the actual circumference.
2. Choose one error from above and discuss if it would make "n" too big or too small.
If the measurement of the circumference is too low, that would mean that while filling the balloon with water, we wouldn't have filled it with enough, which would make the volume too low, which would then result in n being too small.
3. Calculate the volume of the balloon mathematically.
2(3.14)r = 31.20 cm
r = 4.97 cm
v = (4/3)(3.14)r^3
v = (4/3)(3.14)(4.97)^3
v = 514 cm^3 = 514 mL
4. Are the two volumes close? Which do you feel is more accurate and why?
705.9 mL - 514 mL = 192 mL greater
I believe that our volume is more accurate because the CO2 released from the reaction filled the balloon to a non-spherical shape, as did the water we filled the balloon with. We measured the circumference in the same area each time, so it was more accurate than a calculated volume, since neither shapes of the balloon were spherical, as the calculations would assume.
5. Give two differences between a real gas and an ideal gas.
Two of the ideal gas laws are that in an ideal gas, there are no interactive forces, meaning none of the particles of gas repulse or attract each other, and that there is no net loss of energy from collisions between the particles and the walls of the container the gas is in. Real gases don't follow these rules perfectly, and in a real gas, some of the particles could repulse/attract each other, and there could be a net loss of energy from the collisions.
6. Would the CO2 you collected in this lab be considered ideal?
The CO2 collected in this lab would not be considered ideal because all non-theoretical gases are real gases.
Advanced Questions:
1. Calculate the mass of CO2 that should be collected for two tablets.
Each tablet had:
1000 mg C6H8O7
1916 mg NaHCO3
We used two tablets, and after finding the theoretical yields, we found that the C6H8O7 would theoretically produce 1.37439g CO2, and the NaHCO3 would theoretically produce 2.00748g CO2. Therefore, the theoretical yield of CO2 would be 1.37g CO2.
2. What percent is the percent yield for the CO2 collected in your sample?
actual/theoretical = 1.26g / 1.37g = 92.0% yield
3. What effect does the fact that CO2 is water soluble have on your calculated "n" value?
The fact that CO2 is water soluble could decrease the n value. This is because the CO2 could have dissolved in the water while the alka seltzer powder was poured into the water in the test tube. If the CO2 dissolved in the water and not all of it gathered in the balloon, the circumference of the balloon could have been smaller than it would have been without dissolving. This would make the amount of water we filled the balloon with smaller, therefore decreasing the volume, and overall decreasing the n value.